ChemicalBook > CAS DataBase List > 3-BENZYL-5-(2-HYDROXYETHYL)-4-METHYLTHIAZOLIUM CHLORIDE

3-BENZYL-5-(2-HYDROXYETHYL)-4-METHYLTHIAZOLIUM CHLORIDE

Product Name
3-BENZYL-5-(2-HYDROXYETHYL)-4-METHYLTHIAZOLIUM CHLORIDE
CAS No.
4568-71-2
Chemical Name
3-BENZYL-5-(2-HYDROXYETHYL)-4-METHYLTHIAZOLIUM CHLORIDE
Synonyms
3-Benzyl-5-(hydroxyethyl)-4-methylthiazolium chloride;3-Benzyl-5-(2-hydroxyethyl)-4-methylthiazol-3-ium chloride;3-Benzyl-4-methyl-5-(2-hydroxyethyl)thiazole-3-ium·chloride;Nsc172802;-3-ium chL;-5-(2-hydroxyethyL;LABOTEST-BB LT00452912;3-Benzyl-5(2-OHEt)-4-mEtthiazolium Cl;3-BENZYL-5-(2-HYDROXYETHYL)-4-METHYLTHIA;2-(3-benzyl-4-methyl-thiazol-3-ium-5-yl)ethanol
CBNumber
CB7689262
Molecular Formula
C13H16ClNOS
Formula Weight
269.79
MOL File
4568-71-2.mol
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3-BENZYL-5-(2-HYDROXYETHYL)-4-METHYLTHIAZOLIUM CHLORIDE Property

Melting point:
142-144 °C(lit.)
storage temp. 
Inert atmosphere,Room Temperature
form 
Crystalline Powder
color 
White
Water Solubility 
Soluble in water.
Sensitive 
Hygroscopic
BRN 
3788921
InChI
InChI=1S/C13H16NOS.ClH/c1-11-13(7-8-15)16-10-14(11)9-12-5-3-2-4-6-12;/h2-6,10,15H,7-9H2,1H3;1H/q+1;/p-1
InChIKey
IWSVLBKHBJGMAA-UHFFFAOYSA-M
SMILES
[N+]1(=CSC(CCO)=C1C)CC1=CC=CC=C1.[Cl-]
CAS DataBase Reference
4568-71-2(CAS DataBase Reference)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36
WGK Germany 
3
HS Code 
29341000
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
256234
Product name
3-Benzyl-5-(2-hydroxyethyl)-4-methylthiazolium chloride
Purity
98%
Packaging
25g
Price
$67.2
Updated
2024/03/01
TCI Chemical
Product number
B1224
Product name
3-Benzyl-5-(2-hydroxyethyl)-4-methylthiazolium Chloride
Purity
>98.0%(HPLC)(T)
Packaging
25g
Price
$95
Updated
2024/03/01
Alfa Aesar
Product number
L08750
Product name
3-Benzyl-5-(2-hydroxyethyl)-4-methylthiazolium chloride, 98%
Packaging
25g
Price
$50.65
Updated
2024/03/01
Alfa Aesar
Product number
L08750
Product name
3-Benzyl-5-(2-hydroxyethyl)-4-methylthiazolium chloride, 98%
Packaging
100g
Price
$150.65
Updated
2024/03/01
AK Scientific
Product number
J56321
Product name
3-Benzyl-5-(2-hydroxyethyl)-4-methylthiazolium chloride
Packaging
100g
Price
$173
Updated
2021/12/16
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3-BENZYL-5-(2-HYDROXYETHYL)-4-METHYLTHIAZOLIUM CHLORIDE Chemical Properties,Usage,Production

Uses

3-Benzyl-5-(2-hydroxyethyl)-4-methylthiazolium chloride, aliphatic aldehydes undergo the acyloin condensation in the presence of this catalyst and mild base. It acts as a catalyst for the addition of aliphatic and heterocyclic aldehydes to α,β-unsaturated ketones, nitriles and esters.

Purification Methods

Purify the chloride by recrystallisation from EtOH or H2O. If placed in a bath at 125o and heated at 2o/minute, the melting point is 140.5-141.4o. [Livermore & Sealock J Biol Chem 167 699 1947, Maier & Metzler J Am Chem Soc 79 4386 1957, Beilstein 27 III/IV 1758.]

3-BENZYL-5-(2-HYDROXYETHYL)-4-METHYLTHIAZOLIUM CHLORIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from 3-BENZYL-5-(2-HYDROXYETHYL)-4-METHYLTHIAZOLIUM CHLORIDE manufacturers

Career Henan Chemical Co
Product
3-BENZYL-5-(2-HYDROXYETHYL)-4-METHYLTHIAZOLIUM CHLORIDE 4568-71-2
Price
US $1.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
1ton
Release date
2018-08-13

4568-71-2, 3-BENZYL-5-(2-HYDROXYETHYL)-4-METHYLTHIAZOLIUM CHLORIDERelated Search:


  • 3-Benzyl-4-methyl-5-(2-hydroxyethyl)thiazole-3-ium·chloride
  • 3-Benzyl-4-methyl-5-(2-hydroxyethyl)thiazolium·chloride
  • 5-(2-Hydroxyethyl)-3-benzyl-4-methylthiazole-3-ium·chloride
  • Nsc172802
  • 3-BENZYL-5-(2-HYDROXYETHYL)-4-METHYLTHIA
  • 3-Benzyl-5-(2-hydroxyethyl)-4-MethylthiazoliuM chloride 98%
  • 3-Benzyl-5-(2-hydroxyethyl)-4-methylthiazol-3-ium chloride
  • 3-Benzyl-5(2-OHEt)-4-mEtthiazolium Cl
  • 3-BENZYL-5-(-2-HYDROXYETHYL)-4-METHYL 1,3-THIAZOLIUM CHLORIDE
  • 3-BENZYL-5-(2-HYDROXYETHYL)-4-METHYLTHIAZOLIUM CHLORIDE
  • LABOTEST-BB LT00452912
  • 3-Benzyl-5-(hydroxyethyl)-4-methylthiazolium chloride
  • 3-Benzyl-5(2-hydroxyethyl)-4-methylthiazolium chloride, GC 98%
  • 5-(2-Hydroxyethyl)-4-methyl-3-benzylthiazolium chloride
  • 3-Benzyl-4-methyl-3-azoniathiazole-5-ethanol·chloride
  • 3-Benzyl-4-methyl-5-(2-hydroxyethyl)-3-azoniathiazole·chloride
  • Thiazolium, 5-(2-hydroxyethyl)-4-methyl-3-(phenylmethyl)-, chloride
  • 3-Benzyl-5-(2-hydroxyethyl)-4-methylthiazolium Chloride &gt
  • 3-Benzyl-5-(2-hydroxyethyl)-4-methylthiazolium chloride, 98%, for synthesis
  • -3-ium chL
  • -5-(2-hydroxyethyL
  • 2-(3-benzyl-4-methyl-thiazol-3-ium-5-yl)ethanol
  • 2-(3-benzyl-4-methyl-1,3-thiazol-3-ium-5-yl)ethanol
  • 3-Benzyl-5-(2-via ethyl)-4-methylThiazole chloride
  • 3-Blin-5-(2-hydroxyethyl)-4-AChlorinated prazole
  • 4568-71-2
  • 4658-71-2
  • C13H16NOSCl
  • Phase Transfer Catalysts
  • Synthetic Reagents
  • Heterocyclic Ammonium Salts
  • Heterocyclic Ammonium Salts
  • Greener Alternatives: Catalysis
  • Phase Transfer Catalysts